64362-19-2

Basic information

• Product Name: 1,4-Epoxynaphthalene-2,3-dicarboxylic acid, 1,4-dihydro-1,4-diphenyl-, dimethyl ester
• CAS NO: 64362-19-2
• Molecular Formula: C26H20O5
• Molecular Weight: 412.442
• Mol File: 64362-19-2.mol

Chemical Properties

• CAS DataBase Reference: 1,4-Epoxynaphthalene-2,3-dicarboxylic acid, 1,4-dihydro-1,4-diphenyl-, dimethyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: 1,4-Epoxynaphthalene-2,3-dicarboxylic acid, 1,4-dihydro-1,4-diphenyl-, dimethyl ester(64362-19-2)
• EPA Substance Registry System: 1,4-Epoxynaphthalene-2,3-dicarboxylic acid, 1,4-dihydro-1,4-diphenyl-, dimethyl ester(64362-19-2)

Safety Data

• Hazardous Substances Data: 64362-19-2(Hazardous Substances Data)

Upstream product

• 34082-81-0 8-Oxo-1,9-diphenyl-12-oxa-tricyclo[7.2.1.0^2,7]dodeca-2⁽⁷⁾,3,5,10-tetraene-10,11-dicarboxylic acid dimethyl ester 
• 5471-63-6 1,3-diphenylisobenzofuran 
• 762-42-5 dimethyl acetylenedicarboxylate 

Downstream Products

• 83164-99-2 dimethyl 1,4-diphenylnaphthalene-2,3-dicarboxylate 
• 64362-20-5 dimethyl 1-oxo-2,4-diphenyl-1,2-dihydronaphthalene-2,3-dicarboxylate 

Relevant articles and documents

Regioselective arene homologation through rhenium-catalyzed deoxygenative aromatization of 7-oxabicyclo[2.2.1]hepta-2,5-dienes

Combined use of oxorhenium catalysts with triphenyl phosphite as an oxygen acceptor allowed efficient deoxygenative aromatization of oxabicyclic dienes. The reaction proceeded under neutral conditions and was compatible with various functional groups. Combining this deoxygenation with regioselective bromination and trapping of the generated aryne with furan resulted in benzannulative π-extension at the periphery of the PAHs. This enabled direct use of unfunctionalized PAHs for extension of π-conjugation. Iteration of the transformations increased the number of fused-benzene rings one at a time, which has the potential to alter the properties of PAHs by fine-tuning the degree of π-conjugation, shape, and edge topology.

Synthetic transformation of 1,3-diarylisobenzofuran-DMAD adducts: A facile preparation of tri-substituted α-naphthols

1,3-Diarylisobenzofuran-DMAD adducts upon reaction with BF3·OEt2 in DCM at room temperature underwent a regiospecific 1,2-aryl migration followed by the Krapcho decarboxylation to give tri-substituted α-naphthols in good yields.

Phototransformations of Epoxyindanone Adducts. Steady-State and Laser Flash Photolysis Studies

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