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1,3,4,6-Tetrathiapentalene-2,5-dione is a sulfur-rich heterocyclic compound characterized by a fused dithiole-dithiolone structure with two carbonyl groups at the 2- and 5-positions. It is also known by alternative names such as [1,3]Dithiolo[4,5-d]-1,3-dithioledione and Thiapendione. 1,3,4,6-TETRATHIAPENTALENE-2,5-DIONE exhibits unique electronic and structural properties due to its conjugated system and high sulfur content, making it of interest in materials science and organic chemistry for applications such as conductive polymers or redox-active materials. Its reactivity and potential utility stem from the presence of both thiocarbonyl and carbonyl functionalities within a rigid polycyclic framework.

64394-45-2

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64394-45-2 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 64394-45-2 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 6,4,3,9 and 4 respectively; the second part has 2 digits, 4 and 5 respectively.
Calculate Digit Verification of CAS Registry Number 64394-45:
(7*6)+(6*4)+(5*3)+(4*9)+(3*4)+(2*4)+(1*5)=142
142 % 10 = 2
So 64394-45-2 is a valid CAS Registry Number.
InChI:InChI=1/C4O2S4/c5-3-7-1-2(9-3)10-4(6)8-1

64394-45-2SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 12, 2017

Revision Date: Aug 12, 2017

1.Identification

1.1 GHS Product identifier

Product name 1,3,4,6-Tetrathiapentalene-2,5-Dione

1.2 Other means of identification

Product number -
Other names 1,3,4,6-TETRATHIAPENTALENE-2,5-DIONE

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

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Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:64394-45-2 SDS

64394-45-2Relevant academic research and scientific papers

[1,3]-Dithiolo-[4,5-d ][1,3-dithiole]-2,5-dione

Müller, Harald,Bourcet, Léa

, p. 1817 - 1822 (2021/11/04)

A safe, three-step reaction sequence to [1,3]-dithiolo-[4,5- d ][1,3-dithiole]-2,5-dione starting from carbon disulfide is presented. Optimized reaction conditions, rigorous purification, and full characterization of all intermediates provide reproducibly a final product of superior quality with a melting point of 181 °C (dec.).

TRANSITION-METAL 1,2-DIHETEROLENES AND POLYHETEROTETRAHETERAFULVALENES: PRECURSORS OF CONDUCTING SOLIDS

Papavassiliou, G. C.,Kakoussis, V. C.,Lagouvardos, D. J.,Mousdis, G. A.

, p. 171 - 184 (2007/10/02)

Methods for synthesis and properties of oxygen-, sulfur-, selenium-, and nitrogen-containing transition-metal 1,2-diheterolenes and polyheterotetraheterafulvalenes are described.Also, the preparation and properties of some conducting salts based on these compounds are briefly discussed.

Tetrathiafulvalenes. XIX. Synthesis and Properties of Electron Conducting Poly-Dithiolene Complexes with Ethylene Tetrathiolat and Tetrathiafulvalene Tetrathiolat as Bridge Ligands

Poleschner, H.,John, W.,Hoppe, F.,Fanghaenel, E.

, p. 957 - 975 (2007/10/02)

-Dithiolo-1,3-dithiol-2,5-dione 7 and 5-(5-oxo-dithiolo-1,3-dithiole-2-ylidene)-dithiolo-1,3-dithiol-2-one 8 were synthesized from 1,3-dithiole-2-thione-4,5-dithiolat.The ligands react with salts of iron, cobalt, nickel

ELECTROCHEMICAL REDUCTION OF CARBON DISULFIDE. SYNTHESIS OF CARBON SULFIDE HETEROCYCLES

Hurley, Michael F.,Chambers, James Q.

, p. 775 - 778 (2007/10/02)

Detailed procedures for the electrochemical reduction of carbon disulfide in N,N-dimethylformamide and acetonitrile are given.The synthetic utility of the method is demonstrated by the preparation of several thio-substituted derivatives of tetrathiafulvalene.Cyclic voltammograms of the tetrapotassium salt of the tetrathio anion of tetrathiofulvalene indicate four successive electron-transfer steps and in situ formation of a C6S8 species.Oxidation of the CS2 electrolysis solutions produces a compound which is tentatively identified as dithiolo-1,2,3-trithiole-5-thione.

Tetrathiapentalene and tetraselenapentalene compounds

-

, (2008/06/13)

This application is concerned with tetrathiapentalene and tetraselenapentalene compounds. Specifically, it is concerned with 1, 3, 4, 6-tetrathia-2, 5-dihetero-pentalene and 1, 3, 4, 6-tetraselena-2,5-dihetero-pentalene compounds having the formula STR1 w

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