64447-82-1

Basic information

• Product Name: (2S,3S,6S)-6-(benzyloxy)-2-methyltetrahydro-2H-pyran-3-ol
• Synonyms: (2S,3S,6S)-6-(benzyloxy)-2-methyltetrahydro-2H-pyran-3-ol
• CAS NO: 64447-82-1
• Molecular Weight: 222.284
• Mol File: 64447-82-1.mol

Chemical Properties

• CAS DataBase Reference: (2S,3S,6S)-6-(benzyloxy)-2-methyltetrahydro-2H-pyran-3-ol(CAS DataBase Reference)
• NIST Chemistry Reference: (2S,3S,6S)-6-(benzyloxy)-2-methyltetrahydro-2H-pyran-3-ol(64447-82-1)
• EPA Substance Registry System: (2S,3S,6S)-6-(benzyloxy)-2-methyltetrahydro-2H-pyran-3-ol(64447-82-1)

Safety Data

• Hazardous Substances Data: 64447-82-1(Hazardous Substances Data)

Upstream product

• 247244-65-1 L-aculose 
• 4208-64-4 (S)-1-(2-furanyl)ethanol 
• 1192-62-7 1-(2-furyl)-1-ethanone 

Relevant articles and documents

Divergent de novo synthesis of all eight stereoisomers of 2,3,6-trideoxyhexopyranosides and their oligomers

All eight possible stereoisomers of 2,3,6-trideoxyhexopyranosides are prepared systematically from furan derivatives by a sequence of Achmatowicz rearrangement, Pd-catalysed glycosidation, and chiral catalyst-controlled tandem reductions. This sequence provides access to all possible stereoisomers of naturally occurring rhodinopyranosides, amicetopyranosides, disaccharide narbosine B, and other unnatural oligomeric 2,3,6-trideoxyhexopyranosides. It comprises a unique and systematic strategy for the de novo synthesis of deoxysugars.

Catalytic Asymmetric Synthesis of All Possible Stereoisomers of 2,3,4,6-Tetradeoxy-4-Aminohexopyranosides

We recently developed a divergent strategy for the synthesis of all eight possible 2,3,6-trideoxyhexopyranosides with three stereogenic centers. However, the diastereoselectivity for one of the three stereogenic centers was low and it was not controlled b