64449-33-8

Basic information

• Product Name: 2-Allyl-3-methyl-1,4-naphthoquinone
• Synonyms: 2-Allyl-3-methyl-1,4-naphthoquinone;2-Methyl-3-(2-propenyl)-1,4-naphthalenedione
• CAS NO: 64449-33-8
• Molecular Formula: C14H12O2
• Molecular Weight: 212.24
• Mol File: 64449-33-8.mol
• Article Data: 11

Chemical Properties

• Appearance: /
• CAS DataBase Reference: 2-Allyl-3-methyl-1,4-naphthoquinone(CAS DataBase Reference)
• NIST Chemistry Reference: 2-Allyl-3-methyl-1,4-naphthoquinone(64449-33-8)
• EPA Substance Registry System: 2-Allyl-3-methyl-1,4-naphthoquinone(64449-33-8)

Safety Data

• Hazardous Substances Data: 64449-33-8(Hazardous Substances Data)

Upstream product

• 58-27-5 menadione 
• 106-95-6 allyl bromide 
• 614-45-9 tert-Butyl peroxybenzoate 
• 65593-24-0 3-(propen-3-yl)-1,4-naphthoquinone 
• 18330-27-3 2-ethylidene-pent-4-enoic acid methyl ester 
• 27613-27-0 3-oxo-1,3-dihydroisobenzofuran-1-carbonitrile 
• 1431987-65-3 C₁₉H₁₈O₂ 
• 53772-33-1 2-bromo-3-methyl-1,4-dimethoxynaphthalene 
• 762-72-1 allyl-trimethyl-silane 
• 24850-33-7 allyltributylstanane 
• 71573-68-7 2‐allyl‐1,4‐dimethoxy‐3‐methylnaphthalene 
• 66557-16-2 2,3-benzo-1-allyl-1-hydroxy-6-methylcyclohexa-2,4-dien-4-one 

Relevant articles and documents

Bioinspired Photoredox Benzylation of Quinones

3-Benzylmenadiones were obtained in good yield by using a blue-light-induced photoredox process in the presence of Fe(III), oxygen, and γ-terpinene acting as a hydrogen-atom transfer agent. This methodology is compatible with a wide variety of diversely substituted 1,4-naphthoquinones as well as various cheap, readily available benzyl bromides with excellent functional group tolerance. The benzylation mechanism was investigated and supports a three-step radical cascade with the key involvement of the photogenerated superoxide anion radical.

Synthesis of Vitamin K and Related Naphthoquinones via Demethoxycarbonylative Annulations and a Retro-Wittig Rearrangement

Anionic annulations of 3-nucleofugal phthalides with α-alkyl(aryl)acrylates involving a demethoxycarbonylation provide a succinct synthesis of vitamin K and related naphthoquinones. Also reported is a new cascade reaction stemming from a Cope-retro-Wittig rearrangement. This cascade leads to direct formation of 1-hydroxy-4-prenyloxynaphthalene-2-carboxylates from the corresponding α-prenyl acrylate acceptors.

QUINONE BASED NITRIC OXIDE DONATING COMPOUNDS

The present invention relates to nitric oxide donor compounds having a quinone based structure, to processes for their preparation and to their use in the treatment of pathological conditions where a deficit of NO plays an important role in their pathogenesis.