64450-63-1Relevant academic research and scientific papers
IODIDE ION PROMOTION BENZYL CHLORIDE-BORATE ESTER CARBONYLANION REACTIONS
Alper, Howard,Hamel, Nathalie,Smith, David J. H.,Woell, James B.
, p. 2273 - 2274 (2007/10/02)
Esters are isolated in fine yields from the rhodium(I) catalyzed reaction of benzyl chlorides with borate esters and carbon monoxide, in the presence of potassium iodide.
SYNTHESIS OF ESTERS BY RHODIUM(I) CATALYZED BORATE ESTER-BENZYLIC BROMIDE CARBONYLATION REACTIONS
Woell, James B.,Alper, Howard
, p. 3791 - 3794 (2007/10/02)
Benzylic halides react with trialkylborates and carbon monoxide, in the presence of 1,5-hexadienerhodium chloride dimer, to give esters in excellent yields.The reaction is applicable to the synthesis of primary, secondary and even tertiary esters.
