64451-49-6Relevant academic research and scientific papers
THE SYNTHESIS, CRYSTAL AND MOLECULAR STRUCTURES OF TRIPHENYL(PHENYLTHIO)SILANE, Ph3SiSPh, and of bis(μ-THIOPHENOLATO)BIS, 2
Lucas, C. Robert,Newlands, Michael J.,Gabe, Eric J.,Lee, Florence L.
, p. 898 - 902 (2007/10/02)
Preparations and X-ray structure determinations are described for Ph3SiSPh and 2.The compound Ph3SiSPh crystallizes in space group Pcab with a=15.260 Angstroem, b=15.968 Angstroem, c=16.757 Angstroem, Z=8, dcalc=1.20 g cm-3
Thioether complexes of tungsten hexacarbonyl
Lucas, C. Robert
, p. 1758 - 1763 (2007/10/02)
The preparation of a series of organic and organometallic thioethers R3MSR' (M = C,Si,Ge, or Sn) is reported.From these, several new compounds of type 1 are synthesized, some of which contain para-substituted aryl functions for R and R'.In hexane solution in the carbonyl streching region of the ir the uv there is evidence for a degree of multiple bonding, at least in the M - S - WW - CO portion of these molecules.Multiple bonding extending into aromatic R or R'is small or non-existent and cannot be assessed precisely because of spontaneous decomposition of the complexes.All the complexes undergo a thermally initiated decomposition, the case of which depends on the nature of R, R', and M.The unusual W(I) thiolate cis-2 is the termal decomposition product.
