64474-85-7

Basic information

• Product Name: 3-(acetylamino)-2,3,6-trideoxyhexopyranose
• CAS NO: 64474-85-7
• Molecular Formula: C₈H₁₅NO₄
• Molecular Weight: 189.209
• Mol File: 64474-85-7.mol
• Article Data: 9

Chemical Properties

• Boiling Point: 458.3°C at 760 mmHg
• Flash Point: 231°C
• Density: 1.25g/cm³
• Vapor Pressure: 2.51E-10mmHg at 25°C
• Refractive Index: 1.514
• CAS DataBase Reference: 3-(acetylamino)-2,3,6-trideoxyhexopyranose(CAS DataBase Reference)
• NIST Chemistry Reference: 3-(acetylamino)-2,3,6-trideoxyhexopyranose(64474-85-7)
• EPA Substance Registry System: 3-(acetylamino)-2,3,6-trideoxyhexopyranose(64474-85-7)

Safety Data

• Hazardous Substances Data: 64474-85-7(Hazardous Substances Data)

Upstream product

• 108-24-7 acetic anhydride 
• 38280-94-3 4,5-O-isopropylidene-erythro-hex-2-enoic acid methyl ester 
• 75712-50-4 3-Amino-3-((4R,5S)-2,2,5-trimethyl-[1,3]dioxolan-4-yl)-propionamide 
• 96796-65-5 methyl 2,6-dideoxy-3-O-methanesulphonyl-4-O-methoxymethyl-α-L-ribo-hexopyranoside 
• 96796-66-6 methyl 3-azido-2,3,6-trideoxy-4-O-methoxymethyl-α-L-arabino-hexopyranoside 
• 96796-64-4 methyl 2,6-dideoxy-4-O-methoxymethyl-α-L-ribo-hexopyranoside 
• 96796-47-3 methyl 3-acetamido-2,3,6-trideoxy-4-O-methoxymethyl-α-L-arabino-hexopyranoside 
• 1002757-16-5 methyl 2,3-O-benzylidene-6-deoxy-4-O-(2-methoxyethoxymethyl)-α-L-mannopyranoside 
• 84765-85-5 methyl 2,6-dideoxy-4-O-(2-methoxyethoxymethyl)-α-L-erythro-hexopyranosid-3-ulose oxime 
• 81348-07-4 methyl 2,6-dideoxy-4-O-(2-methoxyethoxymethyl)-α-L-erythro-hexopyranosid-3-ulose 
• 81348-15-4 methyl 3-acetamido-2,3,6-trideoxy-4-O-(2-methoxyethoxymethyl)-α-L-ribo-hexopyranoside 
• 94944-21-5 (E)-(4S,5R)-4,5-Bis-carbamoyloxy-hex-2-enoic acid ethyl ester 
• 70805-61-7 ethyl 4,5-dihydroxy-2E-hexenoate 
• 84173-36-4 (E)-ethyl 3-((2RS,3RS)-3-methyloxiran-2-yl) acrylate 

Downstream Products

• 81227-34-1 1-O-acetyl-2,3,6-trideoxy-5-O-(p-nitrobenzoyl)-3-(trifluoroacetamido)-D-ribo-hexofuranose 
• 81227-33-0 methyl 2,3,6-trideoxy-5-O-(p-nitrobenzoyl)-3-(trifluoroacetamido)-α-D-ribo-hexofuranoside 
• 81227-36-3 methyl 2,3,6-trideoxy-5-O-(p-nitrobenzoyl)-3-(trifluoroacetamido)-β-D-ribo-hexofuranoside 
• 81227-31-8 methyl 3-acetamido-2,3,6-trideoxy-5-O-(p-nitrobenzoyl)-β-D-ribo-hexofuranoside 
• 81227-28-3 methyl 3-acetamido-2,3,6-trideoxy-5-O-(p-nitrobenzoyl)-α-D-ribo-hexofuranoside 
• 81227-42-1 methyl 2,3,6-trideoxy-5-O-(p-nitrobenzoyl)-3-(p-nitrobenzoylacetamido)-α-D-ribo-hexofuranoside 
• 81227-30-7 3-acetamido-1-O-acetyl-2,3,6-trideoxy-5-O-(p-nitrobenzoyl)-D-ribo-hexofuranose 
• 6605-27-2 methyl 3-acetamido-2,3,6-trideoxy-arabino-β-D,L-hexopyranoside 
• 6605-27-2 methyl 3-acetamido-2,3,6-trideoxy-arabino-α-D,L-hexopyranoside 

Relevant articles and documents

Syntheses of spacer-linked neodisaccharides derived from L-Daunosamine

The preparation of novel head-to-head spacer-linked bisdaunosamine homodimers 8, 15 and 18 is described. The synthesis is achieved by double glycosylation of monosilylated 1,4-butanediol 9 using silyl glycoside 5 as glycosyl donor. Alternatively, olefin metathesis of allyl glycosides α-11 and particularly of α-12 constitutes a second route toward 8 and its unsaturated derivative 15 while non symmetrical dimer 18 has been obtained by cross metathesis of allyl glycosides 11 and 12.

CONVENIENT SYNTHESYS OF L-DAUNOSAMINE AND L-ACOSAMINE

-

THE SYNTHESIS OF 3-ACETAMIDO-2,3,5,6-TETRADEOXY-5-FLUORO-D,L-ribo-HEXOFURANOSE BY THE DIRECT FLUORINATION OF METHYL 3-ACETAMIDO-2,3,6-TRIDEOXY-D,L-arabino-HEXOPYRANOSIDE (METHYL N-ACETYL-D,L-ACOSAMINIDE)

3-Acetamido-2,3,5,6-tetradeoxy-5-fluoro-D,L-ribo-hexofuranose was synthesized by direct, fluorinative dehydroxylation of methyl 3-acetamido-2,3,6-trideoxy-D,L-arabino-hexopyranoside with sulfur tetrafluoride-hydrogen fluoride.The furanose form and the ribo configuration, indicated by 13C- and 1H-n. m. r. spectroscopy, respectively, were confirmed by a single-crystal, X-ray diffraction study.