64494-50-4

Upstream product

• 591-51-5 phenyllithium 
• 420-37-1 trimethoxonium tetrafluoroborate 
• 74171-10-1 Fe(CO)2(C(OCH₃)C₆H₅)(C₅H₅)⁽¹⁺⁾*PF₆^(1-) = [Fe(CO)2(C(OCH₃)C₆H₅)(C₅H₅)]PF₆ 
• 74-88-4 methyl iodide 

Downstream Products

• 104832-41-9 (C₅H₅)(CO)(P(C₆H₅)3)FeCH(C₆H₅)(OCH₃) 
• 117178-89-9 (C₅H₅)(CO)(P(C₂H₅)3)FeCH(OCH₃)C₆H₅ 
• 64494-44-6 Cp(CO)2Fe=CH(C₆H₅)⁽¹⁺⁾ 
• 64494-48-0 (C₅H₅)(CO)((C₆H₅)3P)FeCH(OCH₃)(C₆H₅) 
• 4866-54-0 (2-methyl-cyclopropyl)-benzene 
• 4866-54-0 cis-1-methyl-2-phenylcyclopropane 

Relevant academic research and scientific papers

A method for the synthesis of carbene precursors from aldehydes and the metalates (η5-C5H5)(CO)2Fe- and (η5-C9H7)(CO)2Fe-

Nucleophilic addition of the metalate Cp(CO)2Fe-M+ (M = Na, K) to aldehydes RCHO (R = Ph, CH3, p-OCH3Ph, p-ClPh, p-CH3Ph, p-CF3Ph, o-OCH3Ph, and CH=C(CH3)2) and subsequent capture with ClSi(CH3)3 provided the (α-siloxyalkyl)iron complexes Cp(CO)2FeCH(OSiMe3)R in 42-79% yield. This new reaction was extended to the indenyl-ligated metalate In(CO)2Fe-Na+ with several aldehydes RCHO (R = Ph, CH3, p-OCH3Ph). Treatment of the (α-siloxyalkyl)iron complexes with trimethylsilyl triflate at between -25 and -78 °C, in the presence of alkenes, gave cyclopropanes through iron carbene complexes.

Synthesis and spectral characterization of a series of iron and ruthenium benzylidene complexes, Cp(CO)(L)M=CH(C6H4R)+ (M = Fe, Ru; L = CO, PPh3; R = p-H, p-F, p-CH3, p-OCH3). Barriers to a

The α-ether complexes Cp(CO)2Fe-CH(OCH3)C6H4R (7a, R = H; 7b, R = p-F; 7c, R = p-CH3; 7d, R = p-OCH3; 7e, R = m-OCH3; 7f, R = p-CF3), Cp(CO)2Ru-CH(OCH3

THE PREPARATION OF α-METHOXYALKYLIRON COMPLEXES: PRECURSORS OF SECONDARY CARBENEIRON COMPLEXES

The addition of methyl-, n-butyl-, phenyl-, and p-tolyl-lithium reagents to (C5H5)(CO)2Fe=CHOCH3+ PF6- gives the respective α-methoxyalkyliron complexes in good yield.The addition of vinyllithium or vinylmagnesium bromide to (C5H5)(C