644996-45-2Relevant academic research and scientific papers
Dynamic combinatorial libraries of metalloporphyrins: Templated amplification of disulfide-linked oligomers
Kieran, Amy L.,Bond, Andrew D.,Belenguer, Ana M.,Sanders, Jeremy K. M.
, p. 2674 - 2675 (2003)
Disulfide-linked cyclic porphyrin oligomers from dimer to tetramer can be selected and amplified virtually quantitatively from a dynamic combinatorial library using bis-thiol substituted zinc(II) porphyrin units with appropriate amine donor templates.
Fluorescence-Lifetime Imaging and Super-Resolution Microscopies Shed Light on the Directed- and Self-Assembly of Functional Porphyrins onto Carbon Nanotubes and Flat Surfaces
Mao, Boyang,Calatayud, David G.,Mirabello, Vincenzo,Kuganathan, Navaratnarajah,Ge, Haobo,Jacobs, Robert M. J.,Shepherd, Ashley M.,Ribeiro Martins, José A.,Bernardino De La Serna, Jorge,Hodges, Benjamin J.,Botchway, Stanley W.,Pascu, Sofia I.
, p. 9772 - 9789 (2017)
Functional porphyrins have attracted intense attention due to their remarkably high extinction coefficients in the visible region and potential for optical and energy-related applications. Two new routes to functionalised SWNTs have been established using
Dynamic covalent synthesis of donor-acceptor interlocked architectures in solution and at the solution: Surface interface
Wilson, Hannah,Byrne, Sean,Mullen, Kathleen M.
supporting information, p. 715 - 721 (2015/09/08)
Despite advances in the range of mechanically interlocked architectures that can be synthesized and operated as supramolecular machines, motors and sensors in solution, in many cases their synthesis is laborious and expensive requiring long multistep pathways with extensive purification at each stage. Dynamic covalent chemistry has been shown to overcome problems with traditional kinetically controlled synthetic approaches that often afford low yields of interlocked architectures due to irreversible formation of non-interlocked by-products. Herein, we describe the use of reversible disulfide exchange reactions as a means to assemble catenanes and rotaxanes in organic solutions. Moreover, the application of this thermodynamic approach to assemble interlocked architectures at the solution:surface interface, specifically polymer resins, is discussed.
