64505-63-1

Basic information

• Product Name: 1,4-Naphthalenedione, 2-[(3-methoxyphenyl)amino]-
• CAS NO: 64505-63-1
• Molecular Formula: C17H13NO3
• Molecular Weight: 279.295
• Mol File: 64505-63-1.mol
• Article Data: 7

Chemical Properties

• CAS DataBase Reference: 1,4-Naphthalenedione, 2-[(3-methoxyphenyl)amino]-(CAS DataBase Reference)
• NIST Chemistry Reference: 1,4-Naphthalenedione, 2-[(3-methoxyphenyl)amino]-(64505-63-1)
• EPA Substance Registry System: 1,4-Naphthalenedione, 2-[(3-methoxyphenyl)amino]-(64505-63-1)

Safety Data

• Hazardous Substances Data: 64505-63-1(Hazardous Substances Data)

Upstream product

• 2065-37-4 2-bromo-1,4-naphthoquinone 
• 536-90-3 m-Anisidine 
• 90-15-3 α-naphthol 
• 83-72-7 2-hydroxynaphtho-1,4-quinone 
• 130-15-4 [1,4]naphthoquinone 

Downstream Products

• 1445727-23-0 2-((3-methoxyphenyl)(prop-2-ynyl)amino)naphthalene-1,4-dione 
• 1445727-37-6 1-(3-methoxyphenyl)-1,2-dihydrobenzo[g]quinoline-5,10-dione 

Relevant articles and documents

t-BuOK mediated oxidative coupling amination of 1,4-naphthoquinone and related 3-indolylnaphthoquinones with amines

The transition-metal free amination of 1,4-naphthoquinone and related 3-indolylnaphthoquinones with amines, such as various (hetero)aromatic amine and aliphatic aminevia t-BuOK-mediated oxidative coupling at room temperature has been developed. This react

Synthesis of novel substituted methoxybenzo[2,3-b]carbazole derivatives via C-H functionalization. Experimental and theoretical characterization of their photophysical properties

The novel, highly blue, fluorescent N-methyl-6,11-dimethoxybenzo[2,3-b]carbazole derivatives were prepared by oxidative coupling of anilines with naphthoquinone followed by palladium catalyzed oxidative [Formula presented] functionalization and a one pot

Bodipy derivatives as organic triplet photosensitizers for aerobic photoorganocatalytic oxidative coupling of amines and photooxidation of dihydroxylnaphthalenes

We used iodo-Bodipy derivatives that show strong absorption of visible light and long-lived triplet excited states as organic catalysts for photoredox catalytic organic reactions. Conventionally most of the photocatalysts are based on the off-the-shelf compounds, usually showing weak absorption in the visible region and short triplet excited state lifetimes. Herein, the organic catalysts are used for two photocatalyzed reactions mediated by singlet oxygen ( 1O2), that is, the aerobic oxidative coupling of amines and the photooxidation of dihydroxylnaphthalenes, which is coupled to the subsequent addition of amines to the naphthoquinones, via C-H functionalization of 1,4-naphthoquinone, to produce N-aryl-2-amino-1,4-naphthoquinones (one-pot reaction), which are anticancer and antibiotic reagents. The photoreactions were substantially accelerated with these new iodo-Bodipy organic photocatalysts compared to that catalyzed with the conventional Ru(II)/Ir(III) complexes, which show weak absorption in the visible region and short-lived triplet excited states. Our results will inspire the design and application of new organic triplet photosensitizers that show strong absorption of visible light and long-lived triplet excited state and the application of these catalysts in photoredox catalytic organic reactions.