64532-88-3Relevant academic research and scientific papers
Electron transfer induced reductive cleavage of γ-lactones to carboxylic acids by sodium-hexamethylphosphoric triamide (HMPA)
Mukhopadhyaya, Jayanta K.,Mukhopadhyay, Chhanda,Ghatak, Usha Ranjan
, p. 132 - 136 (2007/10/02)
Sodium-hexamethylphosphoric triamide (HMPA) mediated electron transfer induced reductive cleavage of 1 -> 3 and 1 -> 2 γ-lactones fused in cyclohexane ring gives the corresponding carboxylic acids in good yields.
Total Synthesis of (+/-)-Velloziolone
Snider, Barry B.,Buckman, Brad O.
, p. 4883 - 4888 (2007/10/02)
The first total synthesis of the 9,10-seco-kaurene velloziolone (3) has been accomplished using an atom transfer tandem free-radical cyclization to prepare the 6-methylenebicyclooctan-2-one moiety.The known diol 11 is converted to iodo acetate 10 i
