646030-66-2

Upstream product

• 61540-30-5 3-oxohexanoic acid tert-butyl ester 
• 3249-68-1 ethyl butyroyl acetate 
• 137567-99-8 (3R)-hydroxyhexanoic acid tert-butyl ester 
• 58479-61-1 tert-butylchlorodiphenylsilane 
• 501015-46-9 (2R,3S)-(-)-3-methoxymethoxy-2,4-dimethylpent-4-en-1-ol 
• 501015-63-0 (S)-2-Methyl-pent-4-enoic acid (R)-1-chlorocarbonylmethyl-butyl ester 
• 501015-52-7 (2'S,3R)-(+)-3-(2-methylpent-4-enoyloxy)hexanoic acid 
• 501015-47-0 (2R,3S)-(-)-tert-butyl-(3-methoxymethoxy-2,4-dimethylpent-4-enyloxy)dimethylsilane 
• 501015-48-1 (3S,4R)-(-)-5-(tert-butyldimethylsilanyloxy)-3-methoxymethoxy-4-methylpentan-2-one 
• 501015-51-6 (2'S,3R)-(+)-3-(2-methylpent-4-enoyloxy)hexanoic acid tert-butyl ester 
• 501015-44-7 (2'S,3'R,4S,5R)-(-)-3-(3-hydroxy-2,4-dimethylpent-4-enoyl)-4-methyl-5-phenyloxazolidin-2-one 
• 501015-45-8 (2'S,3'R,4S,5R)-(-)-3-(3-methoxymethoxy-2,4-dimethylpent-4-enoyl)-4-methyl-5-phenyloxazolidin-2-one 
• 501015-49-2 (3S,4R)-(-)-2,5-bis(tert-butyldimethylsilanyloxy)-3-methoxymethoxy-4-methylpent-1-ene 
• 501015-53-8 (3S,4R,2'R,4'S,5'S)-(-)-1-(5-allyl-4-methyltetrahydrofuran-2-yl)-5-(tert-butyldimethylsilanyloxy)-3-methoxymethoxy-4-methylpentan-2-one 

Downstream Products

• 646030-68-4 (1S,6S,9R,13R,15R,17R,19S)-(-)-15-tert-butyldiphenylsilyloxy-6,13,19-trimethyl-11-methylene-9-propyl-8,20-dioxabicyclo[15.2.1]eicosane-7,14-dione 
• 646030-67-3 (1S,6S,9R,13R,14S,15R,17R,19S)-(-)-15-tert-butyldiphenylsilyloxy-14-hydroxy-6,13,19-trimethyl-11-methylene-9-propyl-8,20-dioxabicyclo[15.2.1]eicosan-7-one 

Relevant academic research and scientific papers

Total Syntheses of Amphidinolide T1, T3, T4, and T5

A concise, flexible, and high yielding entry into the family of amphidinolide T macrolides, a series of cytotoxic natural products of marine origin, has been developed. All individual members, except amphidinolide T3 (3), derive from compound 39 as a comm