64609-16-1Relevant academic research and scientific papers
An unexpected rearrangement of pent-4-enofuranosides to cyclopentanones upon hydrogenolysis of the anomeric benzyl group
Nie, Shenyou,Chen, Xiaoping,Ma, Yuyong,Li, Wei,Yu, Biao
, p. 36 - 40 (2016)
During our synthesis toward the unique nucleoside antibiotic A201A, we were surprised to find that a benzyl arabino-pent-4-enofuranoside underwent a Ferrier II-like rearrangement readily to provide the corresponding cyclopentanone derivative in high yield and stereoselectivity upon hydrogenolysis of the anomeric benzyl group.
A simple synthesis of C-8 modified 2-keto-3-deoxy-d-manno-octulosonic acid (KDO) derivatives
Winzar, Renee,Philips, Jessica,Kiefel, Milton J.
scheme or table, p. 583 - 586 (2010/10/02)
This paper describes a simple and efficient method with which to prepare C-8 modified 2-keto-3-deoxy-D-manno-octu-losonic acid (KDO) derivatives from C-5 modified arabinose derivatives. Georg Thieme Verlag Stuttgart.
