646480-70-8

Upstream product

• 621-84-1 O-benzyl carbamate 
• 123-72-8 butyraldehyde 
• 762-72-1 allyl-trimethyl-silane 
• 147169-15-1 benzyl N-<1-((p-methylphenyl)sulfonyl)butyl>carbamate 

Downstream Products

• 312296-93-8 (R)-1-benzyloxycarbonyl-2-propyl-1,2,3,6-tetrahydropyridine 
• 1257863-80-1 benzyl 2-methoxy-6-propylpiperidine-1-carboxylate 
• 1257863-78-7 benzyl 2-propyl-3,4-dihydropyridine-1(2H)-carboxylate 
• 1346704-96-8 (E)-benzyl [1-(phenylsulfonyl)hept-1-en-4-yl]carbamate 

Relevant academic research and scientific papers

A mild and efficient tris(pentafluorophenyl)borane-catalyzed sakurai allylation of N-benzyloxycarbonylamino P-tolylsulfone with allyltrimethylsilane

Tris(pentafluorophenyl)borane, B(C6F5)3, was found to be an efficient catalyst for synthesis of N-Cbzhomoallylic amines using Sakurai allylation of N-benzyloxycarbonyl-amino p-tolylsulfones with allyltrimethylsilane.

Indium triflate-catalyzed allylation reactions of N-sulfonyl aldimines or N-alkoxycarbonylamino p-tolylsulfones with allyltrimethylsilane: Synthesis of protected homoallylic amines

Indium triflate-catalyzed allylation reactions of N-sulfonyl aldimines or N-alkoxyloxycarbonylamino p-tolylsulfone with allyltrimethylsilane have been successfully developed to produce protected homoallylic amines.

Hydroformylation of alkenylamines. Concise approaches toward piperidines, quinolizidines, and related alkaloids

Linear hydroformylation of N-protected allyl- or homoallylamines (cyclohydrocarbonylation: CHC), followed by a reductive amination constitute the two key steps toward convenient routes to aza-heterocycles.

Remarkably mild and efficient catalytic Sakurai reaction of N-alkoxycarbonylamino sulfones with allyltrimethylsilane using indium(III) chloride

The Sakurai reaction of N-alkoxycarbonylamino sulfones with allyltrimethylsilane in the presence of a catalytic amount of indium(III) chloride at room temperature produces the corresponding protected homoallylic amines in high yields.

The first catalytic Sakurai reaction of N-alkoxycarbonylamino sulfones with allyltrimethylsilane

The first Sakurai reaction of N-benzyloxycarbonylamino sulfones with allyltrimethysilane in the presence of a catalytic amount of Bi(OTf) 3.4H2O was investigated. Several solvents were screened for the Sakurai reaction and N-benzylox

Highly efficient three-component synthesis of protected homoallylic amines by bismuth triflate-catalyzed allylation of aldimines

Bismuth triflate catalyzes the allylation of a variety of in situ generated protected aldimines using aldehydes, primary carbamates, and allyltrimethylsilane in a three-component reaction. The reaction proceeds rapidly and affords the corresponding protected homoallylic amine in good yield (up to 86%). Scope and limitations of the aldehyde and carbamate components are reported.