64691-28-7

Upstream product

• 121524-02-5 phenyl-(tri-O-acetyl-1-thio-ξ-D-riboside) 
• 52544-88-4 phenyl 2,3,5-tri-O-acetyl-1-thio-β-D-ribofuranoside 
• 28708-32-9 1,2,3,5-tetra-O-acetyl-D-ribofuranose 
• 4551-15-9 phenylthiotrimethylsilane 
• 13035-61-5 1,2,3,5-tetraacetylribose 
• 17314-33-9 tributyltin phenyl sulfide 
• 108-98-5 thiophenol 

Downstream Products

• 262421-85-2 (2S,3R,3aS,9aR)-5,5,7,7-Tetraisopropyl-2-phenylsulfanyl-tetrahydro-1,4,6,8-tetraoxa-5,7-disila-cyclopentacycloocten-3-ol 
• 153362-34-6 β-phenylthio-2,3-O-isopropylidene-D-ribofuranose 

Relevant academic research and scientific papers

Stereoselective synthesis of nucleosides from 1-thio and 1-seleno glycosides through consecutive 1,2-migration and glycosylation under Mitsunobu conditions

2-Deoxy-2-sulfenyl-arabino-α-nucleosides and 2-deoxy-2-sulfenyl-ribo- β-nucleosides were obtained with excellent stereoselectivity from 1-thio- ribo- and 1-thio-arabino-glycosides under Mitsunobu conditions.

A novel route to a new lactone intermediate for C-nucleosides via an intramolecular sulfonium ylide rearrangement. A formal synthesis of (+)-showdomycin

The lactone of 3,6-anhydro-4,5-O-isopropylidene-2-thiophenoxy-D-allo-heptonic acid was prepared by means of an intramolecular carbenoid-phenylthiofuranose reaction.

Anomeric Configuration Analysis-Extension of the Ring Oxygen Helicity Rule to Aromatic Glycofuranosides

A strong Cotton effect associated with the ring oxygen was studied in aromatic glucofuranosides.Phenyl and phenyl 1-thioglycofuranosides gave a strong band at 180 nm and 200 - 210 nm respectively, similar to the corresponding glycopyranosides, suggesting