647024-48-4Relevant academic research and scientific papers
Enantioselective Nazarov Cyclizations Catalyzed by an Axial Chiral C6F5-Substituted Boron Lewis Acid
Süsse, Lars,Vogler, Maria,Mewald, Marius,Kemper, Benedict,Irran, Elisabeth,Oestreich, Martin
supporting information, p. 11441 - 11444 (2018/08/28)
A chiral variant of B(C6F5)3 with a 3,3′-disubstituted binaphthyl backbone is shown to catalyze Nazarov cyclizations with high levels of enantio- and diastereocontrol. The parent B(C6F5)3 a
The Palladium(II)-Catalyzed Nazarov Reaction
Bee, Cisco,Leclerc, Eric,Tius, Marcus A.
, p. 4927 - 4930 (2007/10/03)
(Equation presented) The PdCl2-catalyzed cyclization of α-alkoxy dienones leads to 2-hydroxycyclopentenones, whereas the Pd(OAc)2-catalyzed reaction leads to cross-conjugated cyclopentenones through an oxidative process.
