64703-98-6Relevant academic research and scientific papers
Chavicol β-D-glucoside, a phenylpropanoid heteroside, benzyl-β-D-glucoside and glycosidically bound volatiles from subspecies of Cedronella canariensis
Coen, Matthias,Engel, Ralf,Nahrstedt, Adolf
, p. 149 - 156 (2007/10/02)
The volatile substances obtained after enzymatic hydrolysis of purified polar extracts from the aerial parts of two subspecies of Cedronella canariensis were shown to be, among others, benzyl alcohol (29.4percent), chavicol (11.6percent), cis-3-hexenol (9.3percent), 2-phenylethanol (8.6percent), cis-pinocarveol (5.1percent), myrtenol (2.2percent), 1-phenylethanol (2.0percent, tentatively), 1-octen-3-ol (1.8percent), 1-hexanol (1.1percent) for ssp. canariensis and chavicol (85.1percent), benzyl alcohol (2.5percent), cis-3-hexenol (2.5percent), 1-octen-3-ol (2.3percent); 1-hexanol (0.8percent) for ssp. anisata.Sugars detected in the polar fraction after hydrolysis were glucose, rhamnose and fructose.The main glycosides obtained from the polar fraction before hydrolysis were chavicol glucoside (6 ppm, ssp. anisata) and benzyl alcohol glucoside (2 ppm, ssp. canariensis).
Structure and Synthesis of Miyaginin, a p-Allylphenyl Glycoside from Lespedeza thunbergii forma macrantha
Ojika, Makoto,Kuyama, Hiroki,Niwa, Haruki,Yamada, Kiyoyuki
, p. 2893 - 2896 (2007/10/02)
The structure of miyaginin previously reported as p-vinylphenyl O-D-xylosyl-(1->6)-D-glucoside without stereochemical assignment of two glycosidic linkages was reinvestigated by spectral and chemical means and shown to be revised as p-allylphenyl O-β-D-xylopyranosyl-(1->6)-β-D-glucopyranoside (p-allylphenyl β-primeveroside).In order to confirm the revised structure, an unambiguous synthesis of miyaginin was performed.
