6472-11-3Relevant academic research and scientific papers
New 2,4,6-substituted 1,3-dioxanes: Synthesis, stereochemistry and thermodynamic data determinations by cis-trans isomers equilibrium
Balog, Mirela,Ramondenc, Yvan,Oprean, Ioan,Grosu, Ion,Ple, Gerard
, p. 389 - 394 (2007/10/03)
The thermodynamic data (A-values) for some substituents located at position 2 of the 1,3-dioxane ring are calculated from the ratio (measured by GC-MS and NMR) of cis and trans isomers of some 2,4,6-substituted-1,3-dioxanes obtained by the condensation reaction of meso 2,4-pentanediol with several aldehydes and ketones. The stereochemistry of these compounds is deduced from high-field NMR experiments.
