64741-06-6Relevant academic research and scientific papers
SYNTHESIS OF β-FLUOROALKYL PHENYL (OR METHYL) THIOETHERS BY SULFUR-ASSISTED HALOGEN EXCHANGE WITH TRIETHYLAMINE TRIS-HYDROFLUORIDE
Saluzzo, C.,Alvernhe, G.,Anker, D.,Haufe, G.
, p. 467 - 479 (2007/10/02)
The exchange of chlorine in β-chloroalkyl phenyl (or methyl) thioethers by fluorine, with anchimeric assistance of sulfur, is very easily realized with the almost neutral fluorinating reagent, Et3N*3HF.The 'one-pot' reactions of alkenes with sulfenyl chlo
ALKENE CARBOSULPHENYLATION AND CARBOSELENYLATION: THE USE OF ALLYLTRIMETHYLSILANE AND O-SILYLATED ENOLATES.
Alexander, Rikki P.,Paterson, Ian
, p. 5911 - 5914 (2007/10/02)
Allyltrimethylsilane, as well as O-silylated enolates, can be alkylated by the PhSCl adducts of alkenes and vinyl ethers (1, X=SPh); the PhSeCl analogues (1, X=SePh), however, are less useful for alkylation purposes due to competing nucleophilic attack at selenium.
