64749-19-5Relevant academic research and scientific papers
ORGANOSILICON HETEROCYCLIC COMPOUNDS. LX. UNSATURATED SILICON-OXYGEN-CONTAINING COMPOUNDS: POTENTIAL SOURCES OF DICHLOROSILANONE
Chernyshev, E. A.,Krasnova, T. L.,Mudrova, N. A.,Bochkarev, V. N.
, p. 1502 - 1509 (2007/10/02)
The thermolysis of a number of unsaturated heterocyclic compounds containing the endocyclic grouping -OSiCl2- is accompanied by the intermediate formation of dichlorosilanone.The introduction of trichlorosilane into the zone of the pyrolysis of these compounds leads to a considerable increase in the extent of their conversion, and the latter is not only an acceptor of dichlorosilanone, for it reacts with intermediate hydrocarbon diradicals.Is is concluded that the process of the thermal breackdown of the compounds studied with the elimination of the intermediate dichlorosilanone is reversible.
