64754-74-1Relevant articles and documents
Phototransformation of carboxin in water. Toxicity of the pesticide and its sulfoxide to aquatic organisms
Dellagreca, Marina,Iesce, Maria Rosaria,Cermola, Flavio,Rubino, Maria,Isidori, Marina
, p. 6228 - 6232 (2007/10/03)
Sunlight exposure of aqueous suspensions of carboxin (1) causes its phototransformation to sulfoxide 2 and minor components. Similar effects are observed in the presence of humic acid or nitrate or at different pH values. Photoproducts 2-9 were isolated by Chromatographic techniques and/or identified by spectroscopic means. Carboxin 1 and its main photoproduct sulfoxide 2 were tested to evaluate acute toxicity to primary consumers typical of the aquatic environment: the rotifer Brachionus calyciflorus and two crustaceans, Daphnia magna and Thamnocephalus platyurus. Chronic tests comprised a producer, the alga Pseudokirchneriella subcapitata, and a consumer, the crustacean Ceriodaphnia dubia.
Additive Pummerer-Initiated Functionalization of Allylic Methyl Groups in Acrylic Acid Derived Systems
King, Russell R.
, p. 5347 - 5349 (2007/10/02)
Elucidation of reaction parameters for the conversion of the additive Pummerer product 2,3-bis(trifluoroacetoxy)-2-methyl-1,4-oxathiane-3-carboxanilide (2) to N-(trifluoroacetyl)-5,6-dihydro-2--1,4-oxathiin-3-carboxanilide (3) w