64773-44-0Relevant academic research and scientific papers
Critical role of catalysts and boranes for controlling the regioselectivity in the rhodium-catalyzed hydroboration of fluoroolefins
Ramachandran, P. Veeraraghavan,Jennings, Michael P.,Brown, Herbert C.
, p. 1399 - 1402 (1999)
(formula presented) Catalytic hydroboration of perfluoroalkylethylenes (RFCH=CH2) with cationic and neutral rhodium complexes allows for selective access to either regioisomeric alcohol after hydroboration with catechol- and pinacolboranes, followed by oxidation with alkaline hydrogen peroxide.
Investigation of the factors controlling the regioselectivity of the hydroboration of fluoroolefins
Ramachandran, P. Veeraraghavan,Jennings, Michael P.
, p. 386 - 387 (2007/10/03)
Either Markovnikov or anti-Markovnikov regioselectivity can be achieved at will during the hydroboration-oxidation of perfluoroalkyl(aryl)ethylenes by varying the hydroborating agent.
