647830-33-9

Upstream product

• 27607-77-8 trimethylsilyl trifluoromethanesulfonate 
• 639464-28-1 2,4-di-O-benzoyl-α-D-mannopyranosyl azide 
• 647830-31-7 3,6-di-O-acetyl-2,4-di-O-benzoyl-α-D-mannopyranosyl trichloroacetimidate 
• 647830-29-3 C₂₄H₂₅NO₉ 

Downstream Products

• 647830-34-0 C₄₀H₃₇N₃O₁₄ 

Relevant academic research and scientific papers

Regioselective glycosylation of 3,6-unprotected mannoside derivatives: Fast access to high-mannose type oligosaccharides

A regioselective glycosylation of 3,6-unprotected mannoside acceptors was investigated. With glycosyl trichloroacetimidate donors, when an excess of trimethylsilyl trifluoromethanesulfonate is used as the catalyst, 6-O-glycosylation exclusively occurred affording a silylated disaccharide that could be involved in a subsequent glycosylation reaction. As an illustration, the fast synthesis of two trisaccharides and one pentasaccharide was achieved.