647842-53-3

Upstream product

• 647842-52-2 2-[(2R,3S,4aR,6R,7S,8aR,9aS,10aS)-3-Benzyloxy-2-methyl-6-triisopropylsilanyloxy-7-(2-triisopropylsilanyloxy-ethyl)-decahydro-1,8,10-trioxa-anthracen-2-yl]-ethanol 
• 647842-48-6 (E)-2-Methyl-4-[(2R,3S,4aR,6S,7R,8aS)-7-triisopropylsilanyloxy-6-(2-triisopropylsilanyloxy-ethyl)-3-trimethylsilanyloxy-octahydro-pyrano[3,2-b]pyran-2-yl]-but-2-enoic acid ethyl ester 
• 647842-49-7 {(2S,3S)-2-Methyl-3-[(2R,3S,4aR,6S,7R,8aS)-7-triisopropylsilanyloxy-6-(2-triisopropylsilanyloxy-ethyl)-3-trimethylsilanyloxy-octahydro-pyrano[3,2-b]pyran-2-ylmethyl]-oxiranyl}-methanol 
• 647842-68-0 (E)-2-Methyl-4-[(2R,3S,4aR,6S,7R,8aS)-7-triisopropylsilanyloxy-6-(2-triisopropylsilanyloxy-ethyl)-3-trimethylsilanyloxy-octahydro-pyrano[3,2-b]pyran-2-yl]-but-2-en-1-ol 
• 647842-69-1 (2R,3S,4aR,6S,7R,8aS)-2-((2S,3S)-3-Methyl-3-vinyl-oxiranylmethyl)-7-triisopropylsilanyloxy-6-(2-triisopropylsilanyloxy-ethyl)-3-trimethylsilanyloxy-octahydro-pyrano[3,2-b]pyran 
• 647842-46-4 Toluene-4-sulfonic acid (2R,3S,4aR,6S,7R,8aS)-3-hydroxy-7-triisopropylsilanyloxy-6-(2-triisopropylsilanyloxy-ethyl)-octahydro-pyrano[3,2-b]pyran-2-ylmethyl ester 
• 647842-50-0 (2R,3S,4aR,6S,7R,8aS)-2-((2S,3S)-3-Methyl-3-vinyl-oxiranylmethyl)-7-triisopropylsilanyloxy-6-(2-triisopropylsilanyloxy-ethyl)-octahydro-pyrano[3,2-b]pyran-3-ol 
• 647842-44-2 (2R,4aR,6R,7S,8aR,9aS,10aS)-2-Phenyl-6-triisopropylsilanyloxy-7-(2-triisopropylsilanyloxy-ethyl)-octahydro-1,3,8,10-tetraoxa-anthracene 
• 647842-47-5 [(2R,3S,4aR,6S,7R,8aS)-7-Triisopropylsilanyloxy-6-(2-triisopropylsilanyloxy-ethyl)-3-trimethylsilanyloxy-octahydro-pyrano[3,2-b]pyran-2-yl]-acetonitrile 
• 647842-45-3 (2R,3S,4aR,6S,7R,8aS)-2-Hydroxymethyl-7-triisopropylsilanyloxy-6-(2-triisopropylsilanyloxy-ethyl)-octahydro-pyrano[3,2-b]pyran-3-ol 
• 647842-43-1 ((2R,4aR,6R,7S,8aR,9aS,10aS)-6-Hydroxy-2-phenyl-octahydro-1,3,8,10-tetraoxa-anthracen-7-yl)-acetic acid ethyl ester 
• 647842-41-9 (E)-3-[(2R,4aR,6S,7R,8aS)-6-(2-Hydroxy-ethyl)-2-phenyl-hexahydro-pyrano[3,2-d][1,3]dioxin-7-yloxy]-acrylic acid ethyl ester 
• 647842-40-8 (2R,4aR,6S,7R,8aS)-6-[2-(tert-Butyl-dimethyl-silanyloxy)-ethyl]-2-phenyl-hexahydro-pyrano[3,2-d][1,3]dioxin-7-ol 
• 647842-42-0 (E)-3-[(2R,4aR,6S,7R,8aS)-6-(2-Oxo-ethyl)-2-phenyl-hexahydro-pyrano[3,2-d][1,3]dioxin-7-yloxy]-acrylic acid ethyl ester 

Downstream Products

• 1055039-96-7 [(2S,3R,4aS,6S,7R,8aS,9aR,10aR)-6-Benzyloxy-7-(2-benzyloxy-ethyl)-7-methyl-3-triisopropylsilanyloxy-decahydro-1,8,10-trioxa-anthracen-2-yl]-acetic acid 
• 647842-60-2 [6-benzyloxy-7-(2-benzyloxy-ethyl)-3-hydroxy-7-methyl-decahydro-1,8,10-trioxa-anthracen-2-yl]-acetic acid 5-(4-methoxy-benzyloxy)-6-[2-(4-methoxy-benzyloxy)-ethyl]-2,6-dimethyl-2-vinyl-tetrahydro-pyran-3-yl ester 
• 647842-59-9 [6-benzyloxy-7-(2-benzyloxy-ethyl)-7-methyl-3-triisopropylsilanyloxy-decahydro-1,8,10-trioxa-anthracen-2-yl]-acetic acid 5-(4-methoxy-benzyloxy)-6-[2-(4-methoxy-benzyloxy)-ethyl]-2,6-dimethyl-2-vinyl-tetrahydro-pyran-3-yl ester 

Relevant academic research and scientific papers

Convergent synthesis of the A-F ring segment of yessotoxin and adriatoxin

A convergent synthesis of the A-F ring segment of yessotoxin and adriatoxin was achieved via the intramolecular allylation of an α-chloroacetoxy ether and subsequent ring-closing metathesis.