64789-02-2Relevant academic research and scientific papers
Nickel-Catalyzed Thiolation of Aryl Halides and Heteroaryl Halides through Electrochemistry
Liu, Dong,Ma, Hong-Xing,Fang, Ping,Mei, Tian-Sheng
, p. 5033 - 5037 (2019)
Transition-metal-catalyzed coupling reactions are useful tools for synthesizing aryl sulfur compounds. However, conventional transition-metal-catalyzed thiolation of aryl bromides and chlorides typically requires the use of strong base under elevated reaction temperature. Herein, we report the first examples of nickel-catalyzed electrochemical thiolation of aryl bromides and chlorides in the absence of an external base at room temperature using undivided electrochemical cells.
