64810-21-5Relevant articles and documents
Dynamic Kinetic Sensitization of β-Dicarbonyl Compounds—Access to Medium-Sized Rings by De Mayo-Type Ring Expansion
Glorius, Frank,Guldi, Dirk M.,Henkel, Christian,James, Michael J.,Mai, Lukas A.,Paulisch, Tiffany O.,Strieth-Kalthoff, Felix
supporting information, (2021/12/27)
Herein, we present a photocatalyzed two-carbon ring expansion of β-dicarbonyl compounds with unactivated olefins that provides facile access to medium-sized rings. Selective sensitization of the substoichiometric enol tautomer enables reactivity of substr