64815-25-4Relevant academic research and scientific papers
Mechanistic insight into the formation of phosphaferrocene
Bitta, Joachim,Fassbender, Stefan,Reiss, Guido,Ganter, Christian
, p. 2394 - 2397 (2008/10/09)
The thermal reaction between [CpFe(CO)2]2 and 1-tert-butyl-3,4-dimethylphosphole leading to phosphaferrocene has been studied with respect to its mechanistic characteristics. Isobutene was identified as the only product originating from the tBu group, suggesting a nonradical pathway which involves β-H elimination from the intermediately formed [CpFe(CO)2-tBu].
