64833-13-2Relevant academic research and scientific papers
Zirconoarylation of alkynes through p-chloranilpromoted reductive elimination of arylzirconates
Yan, Xiaoyu,Chen, Chao,Xi, Chanjuan
, p. 528 - 534 (2014)
A novel method for the zirconoarylation of alkynes was developed. TCQ-promoted reductive elimination of arylzirconate [LiCp2ZrAr(RC=CR) ], which was prepared by the reaction of zirconocene-alkyne complexes with aryllithium compounds, afforded trisubstituted alkenylzirconocenes. This reaction can afford multi-substituted olefins with high stereoselectivity.
