64839-29-8

Upstream product

• 935670-67-0 (1R,2R,6S)-3-methyl-6-(1-methylethenyl)cyclohex-3-ene-1,2-diol 
• 5113-93-9 (1R)-trans-p-menth-2-ene 
• 1124-26-1 (+/-)-(3R,6S)-3-isopropyl-6-methyl-1-cyclohexene 
• 1124-26-1 (+/-)-(3R,6R)-3-isopropyl-6-methyl-1-cyclohexene 
• 34315-76-9 p-menthane-2,3-dione 
• 89-81-6 piperitone 
• 155419-08-2 (3S,6R)-3-Isopropyl-6-methyl-cyclohexane-1,2-diol 

Downstream Products

• 112506-98-6 (1R,2S,3R,4S)-3-(3,5-dinitro-benzoyloxy)-p-menthan-2-ol 
• 102748-64-1 (1RS,2RS,3SR,4RS)-2,3-bis-(3,5-dinitro-benzoyloxy)-p-menthane 
• 115387-81-0 (1RS,2SR,3RS,4SR)-2,3-bis-(3-nitro-benzoyloxy)-p-menthane 
• 102748-64-1 (1RS,2SR,3SR,4RS)-2,3-bis-(3,5-dinitro-benzoyloxy)-p-menthane 
• 102748-64-1 (1RS,2RS,3RS,4SR)-2,3-bis-(3,5-dinitro-benzoyloxy)-p-menthane 
• 102748-64-1 (1RS,2RS,3RS,4RS)-2,3-bis-(3,5-dinitro-benzoyloxy)-p-menthane 
• 102748-64-1 (1RS,2SR,3SR,4SR)-2,3-bis-(3,5-dinitro-benzoyloxy)-p-menthane 
• 102748-64-1 (1RS,2SR,3RS,4RS)-2,3-bis-(3,5-dinitro-benzoyloxy)-p-menthane 
• 115387-81-0 (1RS,2RS,3SR,4SR)-2,3-bis-(3-nitro-benzoyloxy)-p-menthane 

Relevant academic research and scientific papers

Hydrogenation and conformational analysis of (1R,2R,6S)-3-methyl-6-(1- methylethenyl)cyclohex-3-ene-1,2-diol

Hydrogenation of (1R,2R,6S)-3-methyl-6-(1-methylethenyl)cyclohex-3-ene-1,2- diol was studied. Nickel chloride-sodium tetrahydridoborate system turned out to selectively reduce the double bond in the isopropenyl group. The results of conformational analysis of (1R,2R,6S)-3-methyl-6-(1-methylethenyl)cyclohex-3- ene-1,2-diol and its partly and completely hydrogenated derivatives were in a good agreement with the NMR data. Pleiades Publishing, Ltd., 2010.

Insight into acid-mediated asymmetric spirocyclization in the presence of a chiral diol

Asymmetric spirocyclization based on intramolecular conjugate addition using a combination of a Lewis acid and an optically active cyclohexane-1,2-diol has been studied in connection with 1) the effect of substituents on the cyclohexane-1,2-diol and 2) th