648418-76-2Relevant academic research and scientific papers
A tris(carbene) constructed with stable triplet carbene units
Tsuchiya, Yoko,Matsuno, Masayoshi,Itoh, Tetsuji,Hirai, Katsuyuki,Tomioka, Hideo
, p. 2037 - 2050 (2007/10/03)
Bis[10-(4-t-butyl-2,6-dimethylphenyl)-9-anthryl]diazomethane, which can generate a fairly stable triplet carbene that can survive for even a week in solution at room temperature, was shown to be stable enough to undergo a Sonogashira coupling reaction. Th
Preparation of Oligodiazo Compounds by Using the Suzuki Coupling Reaction and Characterization of Their Photoproducts
Itoh, Tetsuji,Hirai, Katsuyuki,Tomioka, Hideo
, p. 1130 - 1140 (2007/10/03)
[9-{10-(4-tert-Butyl-2,6-dimethyl)phenyl}anthryl](4-bromo-2, 6-dimethylphenyl)diazomethane was found to be stable enough to survive under Suzuki coupling conditions and underwent mono-, di-, and trisubstitution with benzene mono-, di-, and triboronic acid
Preparation of bis(diazo) compounds incorporated into butadiyne and thiophene units, and generation and characterization of Bis(carbene) from these compounds
Itoh, Tetsuji,Morisaki, Fumika,Hirai, Katsuyuki,Tomioka, Hideo
, p. 5870 - 5880 (2007/10/03)
[9-{10-(4-t-Butyl-2,6-dimethyl)phenyl}anthryl](4-bromo-2,6-dimethylphenyl) diazomethane(1-N2) was found to be stable enough to survive under Sonogashira and Suzuki coupling reaction conditions, and bis(diazo) compounds incorporated into the 1,4
A Triplet Carbene Surviving a Week in Solution at Room Temperature
Iwamoto, Eri,Hirai, Katsuyuki,Tomioka, Hideo
, p. 14664 - 14665 (2007/10/03)
A stable triplet carbene, having a lifetime at 25 °C of 14.5 days in a dilute benzene solution, was realized by simply changing the substituent at the 10 position of the previously most persistent carbene, di[9-(10-phenyl)anthryl]carbene, from a phenyl to
