648418-76-2Relevant academic research and scientific papers
A tris(carbene) constructed with stable triplet carbene units
Tsuchiya, Yoko,Matsuno, Masayoshi,Itoh, Tetsuji,Hirai, Katsuyuki,Tomioka, Hideo
, p. 2037 - 2050 (2007/10/03)
Bis[10-(4-t-butyl-2,6-dimethylphenyl)-9-anthryl]diazomethane, which can generate a fairly stable triplet carbene that can survive for even a week in solution at room temperature, was shown to be stable enough to undergo a Sonogashira coupling reaction. Th
Preparation of bis(diazo) compounds incorporated into butadiyne and thiophene units, and generation and characterization of Bis(carbene) from these compounds
Itoh, Tetsuji,Morisaki, Fumika,Hirai, Katsuyuki,Tomioka, Hideo
, p. 5870 - 5880 (2007/10/03)
[9-{10-(4-t-Butyl-2,6-dimethyl)phenyl}anthryl](4-bromo-2,6-dimethylphenyl) diazomethane(1-N2) was found to be stable enough to survive under Sonogashira and Suzuki coupling reaction conditions, and bis(diazo) compounds incorporated into the 1,4
Preparation of Oligodiazo Compounds by Using the Suzuki Coupling Reaction and Characterization of Their Photoproducts
Itoh, Tetsuji,Hirai, Katsuyuki,Tomioka, Hideo
, p. 1130 - 1140 (2007/10/03)
[9-{10-(4-tert-Butyl-2,6-dimethyl)phenyl}anthryl](4-bromo-2, 6-dimethylphenyl)diazomethane was found to be stable enough to survive under Suzuki coupling conditions and underwent mono-, di-, and trisubstitution with benzene mono-, di-, and triboronic acid
A Triplet Carbene Surviving a Week in Solution at Room Temperature
Iwamoto, Eri,Hirai, Katsuyuki,Tomioka, Hideo
, p. 14664 - 14665 (2007/10/03)
A stable triplet carbene, having a lifetime at 25 °C of 14.5 days in a dilute benzene solution, was realized by simply changing the substituent at the 10 position of the previously most persistent carbene, di[9-(10-phenyl)anthryl]carbene, from a phenyl to
