64858-29-3Relevant articles and documents
Metallation of pyridin-2-yldiazines. Use of pyridine ring as ortho-directing group. Diazines. Part 45
Berghian, Camelia,Darabantu, Mircea,Turck, Alain,Plé, Nelly
, p. 9637 - 9644 (2005)
Starting from commercial chlorodiazines, we report the synthesis of pyridin-2-yldiazines. The first lithiation and functionalization of these compounds are reported and the regioselectivity of the metallation is discussed. The functionalization via the metallation reaction, provides a new access to substituted pyridin-2-yldiazines, which could be used as building blocks in supramolecules.
A General, Multimetallic Cross-Ullmann Biheteroaryl Synthesis from Heteroaryl Halides and Heteroaryl Triflates
Dibenedetto, Tarah A.,Kang, Kai,Loud, Nathan L.,Weix, Daniel J.
supporting information, p. 21484 - 21491 (2022/01/03)
Despite their importance to medicine and materials science, the synthesis of biheteroaryls by cross-coupling remains challenging. We describe here a new, general approach to biheteroaryls: the Ni-and Pd-catalyzed multimetallic cross-Ullmann coupling of he
Remarkable catalytic activity of [PdCl2(CH3CN) 2] in Suzuki-Miyaura cross-coupling reaction in aqueous media under mild conditions
Ganesamoorthy,Shanmugasundaram,Karvembu
, p. 118 - 124 (2013/04/23)
[PdCl2(CH3CN)2] (2 mol%) was found to be an efficient catalyst for the Suzuki-Miyaura cross coupling reaction between aryl bromide and aryl boronic acid in water solvent at 45 °C. The scope of the protocol was extended to various aryl bromides and aryl boronic acids. In general, an effective method has been developed for the Suzuki-Miyaura cross coupling reaction by using a phosphine-free Pd catalyst.