64952-14-3Relevant articles and documents
Synthesis of 3-oxagranatane-type alkaloid analogs from carbohydrates
Agócs, Attila,Herczegh, Pál,J?ger, Szilvia,Kiss, László,Batta, Gyula
, p. 235 - 239 (2001)
3-Oxagranatane derivatives have been synthesized from dialdehydes obtained by the periodate oxidation of D-glucopyranosides. Reduction of the carbonyl group and removal of the substituents afforded bicyclic iminosugar analogs.
A stereocontrolled synthesis of 3-acetamido-1,3,5-trideoxy- and 1,3,5,6-tetradeoxy-1,5-imino-d-glucitol
Simak, Ondrej,Stanek, Jan,Moravcova, Jitka
experimental part, p. 966 - 971 (2009/09/05)
3-Acetamido-5-amino-3,5,6-trideoxy-d-glucono-1,5-lactam and 3-acetamido-5-amino-3,5-dideoxy-d-glucono-1,5-lactam were synthesized from corresponding 3-acetamido-3-deoxy-β-d-glucopyranosides in 63% and 35% overall yield, respectively. Acetylation followed by reduction led to the title 3-acetamido-3-deoxy derivatives of both deoxynojirimycin and 1,6-dideoxynojirimycin. The procedure developed is useful for a multi-gram scale.
Semisynthetic ε-(iso)rhodomycins: a new glycosylation variant and modification reactions
Kolar, Cenek,Kneissl, Guenther,Knoedler, Ursula,Dehmel, Konrad
, p. 89 - 100 (2007/10/02)
Synthesis of 7-O-(3-amino-2,3,6-trideoxy-α-L-lyxo-hexopyranosyl)-ε-(iso)rhodomycinones 16 and 17, and their 3'-morpholino derivatives are described.Glycosylation (trimethylsilyl triflate, 10:1 dichloromethane-acetone, -35 deg C) of 1-O-tert-butyldimethyls