649556-56-9Relevant academic research and scientific papers
Different thermal reactivity of a 1,2-thiaphospholo[a]phosphirane in free and metal carbonyl complexed form
Jikyo, Tamaki,Maas, Gerhard
, p. 2794 - 2795 (2003)
The W(CO)5 and Fe(CO)4 complexes of the bicyclic phosphirane 3,5,6,6-tetraphenyl-1-phospha-2-thiabicyclo-[3.1.0]hex-3-ene undergo a thermal 2-phenylphosphirane → dihydrophosphaisoindole ring expansion, while the free phosphirane suffers both a [2 + 1] cycloreversion and a fragmentation yielding a butadienyl sulfide.
