649571-79-9Relevant academic research and scientific papers
1,3-Dipolar cycloaddition between N-benzyl-C-glycosyl nitrones and methyl acrylate en route to glycosyl pyrrolidines
Merino, Pedro,Franco, Santiago,Merchan, Francisco L.,Romero, Pilar,Tejero, Tomas,Uriel, Santiago
, p. 3731 - 3743 (2007/10/03)
1,3-Dipolar cycloaddition reactions between three N-benzyl-C-glycosyl nitrones and methyl acrylate afforded key intermediates for the synthesis of glycosyl pyrrolidines. The best result was obtained with a D-galactose derived nitrone which afforded only one isomer in quantitative yield. Absolute configurations were assigned by applying the Kakisawa's rule and X-ray diffraction methods.
