649748-30-1Relevant academic research and scientific papers
On the reactivity of ascomycin at the binding domain. Part 1: Liberation of the tricarbonyl portion of ascomycin
Baumann, Karl,Bacher, Markus,Damont, Annelaure,H?genauer, Klemens,Steck, Andrea
, p. 10075 - 10087 (2003)
Within the binding domain, ascomycin features the unusual pattern of a masked tricarbonyl moiety, which potentially allows for high structural diversity via simple isomerisation events. Herein, methodologies, allowing the liberation of the tricarbonyl unit by blocking the 14-hydroxy group are reported.
