64997-06-4Relevant academic research and scientific papers
Synthesis of (E)-alkenes via hydroindation of C{triple bond, long}C in InCl3-NaBH4 system
Wang, Chunyan,Yan, Lei,Zheng, Zhiguo,Yang, Deyu,Pan, Yuanjiang
, p. 7712 - 7717 (2007/10/03)
In InCl3-NaBH4-MeCN system, terminal aryl alkynes could couple with aryl iodides and bromides to give disubstituted alkenes via hydroindation of C{triple bond, long}C. In the similar way, (E)-alkenylsilanes were synthesized via reduction of alkynylsilanes in tetrahydrofuran (THF) in high yields. The processes showed high regio- and stereoselectivity.
AN UMPOLUNG OF ARYL AND VINYL HALIDES USING TRIS-(TRIMETHYLSILYL)ALUMINUM AND APROACH TO META- AND PARA-BRIDGED AROMATICS
Trost, Barry M.,Yoshida, Jun-ichi
, p. 4895 - 4898 (2007/10/02)
Nickel and palladium catalysts effect the chemoselective and stereocontrolled umpolung of aryl and vinyl halides to trimethylsilyl derivatives; this reaction permits a regioselective approach to cyclophanes.
