65001-44-7Relevant academic research and scientific papers
Chemo-, Regio-, and stereoselective trifluoromethylation of styrenes via visible light-driven single-electron transfer (SET) and triplet-triplet energy transfer (TTET) processes
Lin, Qing-Yu,Xu, Xiu-Hua,Qing, Feng-Ling
, p. 10434 - 10446 (2015/02/19)
A process for tunable and chemo-, regio-, and stereoselective photocatalytic trifluoromethylation of styrenes was developed. Thermodynamically stable E-trifluoromethylated alkenes were prepared using Tognis reagent in the presence of Ru(bpy)3Cl2·6H2O under visible light irradiation, whereas less thermodynamically stable Z-trifluoromethylated alkenes were obtained by employing Umemotos reagent and photocatalyst Ir(ppy)3.
Palladium-mediated intramolecular C-N bond formation between tertiary amines and alkenes
Van Der Schaaf, Paul A.,Sutter, Jean-Pascal,Grellier, Mary,Van Mier, Guido P. M.,Spek, Anthony L.,Van Koten, Gerard,Pfeffer, Michel
, p. 5134 - 5144 (2007/10/02)
The reaction of terminal alkenylarenes having either o-(dimethylamino) or o-[(dimethylamino)methyl] substituents with PdCl2(MeCN)2 in MeOH in the presence of NaOAc and PPh3 has been studied. This reaction affords allylic p
