65001-54-9

Basic information

• Product Name: Benzene, 2-(2-butenyl)-1,3,5-trimethyl-, (Z)-
• CAS NO: 65001-54-9
• Molecular Formula: C13H18
• Molecular Weight: 174.286
• Mol File: 65001-54-9.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: Benzene, 2-(2-butenyl)-1,3,5-trimethyl-, (Z)-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, 2-(2-butenyl)-1,3,5-trimethyl-, (Z)-(65001-54-9)
• EPA Substance Registry System: Benzene, 2-(2-butenyl)-1,3,5-trimethyl-, (Z)-(65001-54-9)

Safety Data

• Hazardous Substances Data: 65001-54-9(Hazardous Substances Data)

Upstream product

• 576-83-0 2,4,6-trimethylphenyl bromide 
• 65001-62-9 3-buten-2-yl benzoate 
• 4784-77-4 (E/Z)-crotyl bromide 
• 5980-97-2 mesitylboronic acid 

Relevant articles and documents

Gold-catalyzed allylation of aryl boronic acids: Accessing cross-coupling reactivity with gold

A sp3-sp2 C?C cross-coupling reaction catalyzed by gold in the absence of a sacrificial oxidant is described. Vital to the success of this method is the implementation of a bimetallic catalyst bearing a bis(phosphino)amine ligand. A mechanistic hypothesis is presented, and observable transmetalation, C?Br oxidative addition, and C?C reductive elimination in a model gold complex are shown. We expect that this method will serve as a platform for the development of novel transformations involving redox-active gold catalysts.