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Λ-[(bpy)2Ru(bpym)][PF6]2, also known as Λ-[(bpy)2Ru(4,4'-dimethyl-2,2'-bipyridine)][PF6]2, is a coordination complex consisting of a ruthenium(II) center coordinated to two 2,2'-bipyridine (bpy) ligands and one 4,4'-dimethyl-2,2'-bipyridine (bpym) ligand. The complex has a hexafluorophosphate (PF6) counterion and exhibits chirality, with the Λ-enantiomer being one of the two possible enantiomers. Λ-[(bpy)2Ru(bpym)][PF6]2 is of interest in the field of coordination chemistry and has potential applications in areas such as catalysis, sensing, and luminescent materials due to its unique electronic and optical properties.

65013-23-2

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65013-23-2 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 65013-23-2 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 6,5,0,1 and 3 respectively; the second part has 2 digits, 2 and 3 respectively.
Calculate Digit Verification of CAS Registry Number 65013-23:
(7*6)+(6*5)+(5*0)+(4*1)+(3*3)+(2*2)+(1*3)=92
92 % 10 = 2
So 65013-23-2 is a valid CAS Registry Number.

65013-23-2Upstream product

65013-23-2Downstream Products

65013-23-2Relevant academic research and scientific papers

Chiral-at-metal ruthenium complex as a metalloligand for asymmetric catalysis

Hamelin, Olivier,Rimboud, Mickael,Pecaut, Jacques,Fontecave, Marc

, p. 5354 - 5360 (2007)

The mononuclear [Ru(bpy)2(bpym)][PF6]2 complex (bpy = 2,2′-bipyridine; bpym = 2,2′-bipyrimidine) has been prepared in its enantiopure Λ form. Because of the chelating property of the bipyrimidine moiety, it is possible to use this chiral-at-metal complex as a chiral inorganic ligand for a second metal cation acting as a catalytic center. Here we report the synthesis and the structural characterization of a novel dinuclear Λ-[(bpy)2Ru(bpym)RuCl(p-cymene)]3+ compound (1). The asymmetric-inducing properties of the enantiopure chiral-at-metal metalloligand have been probed during asymmetric transfer hydrogenation to ketones catalyzed by 1. This provides one of the very few illustrations of the potential of this original class of chiral inorganic ligands.

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