65032-86-2

Upstream product

• 996-82-7 sodium diethylmalonate 
• 111080-52-5 1-benzyl-3-bromo-3-carbamoyl-1-piperideinium bromide 
• 952-92-1 1-Benzyl-1,4-dihydronicotinamide 
• 5096-13-9 1-benzylnicotinamide chloride 
• 110-86-1 pyridine 
• 670-54-2 ethenetetracarbonitrile 

Downstream Products

• 16969-45-2 pyridin-1-ium 
• 670-54-2 tetracyanoethylene radical-anion 
• 14778-29-1 1,1,2,2,-tetracyanoethane 
• 111080-52-5 1-benzyl-3-bromo-3-carbamoyl-1-piperideinium bromide 
• 70665-89-3 5-{3-[Benzyl-((E)-2-methoxycarbonyl-vinyl)-amino]-propyl}-isophthalic acid dimethyl ester 
• 70665-88-2 (E)-3-(1-Benzyl-1,4,5,6-tetrahydro-pyridin-3-yl)-acrylic acid methyl ester 
• 70665-87-1 (2E,4E)-1-Benzyl-5-carbamoyl-1,6,7,8-tetrahydro-azocine-3-carboxylic acid methyl ester 
• 81011-19-0 5-{3-[Benzyl-((E)-1,2-bis-methoxycarbonyl-vinyl)-amino]-propyl}-benzene-1,2,3,4-tetracarboxylic acid tetramethyl ester 
• 70665-77-9 (Z)-2-(1-Benzyl-1,4,5,6-tetrahydro-pyridin-3-yl)-but-2-enedioic acid dimethyl ester 
• 13076-43-2 3-(aminocarbonyl)-1-benzylpyridinium bromide 
• 111080-58-1 1-benzyl-2-methylpyrrolidine-2-carboxamide 
• 111080-59-2 1-benzyl-3-bromopiperidine-3-carboxamide 
• 111080-53-6 1-benzyl-2-formylpyrrolidine-2-carboxamide 
• 111080-61-6 1-benzyl-4a-bromooctahydropyrrolo<3,4-b>pyridin-5-one 

Relevant academic research and scientific papers

Better than Nature: Nicotinamide Biomimetics That Outperform Natural Coenzymes

The search for affordable, green biocatalytic processes is a challenge for chemicals manufacture. Redox biotransformations are potentially attractive, but they rely on unstable and expensive nicotinamide coenzymes that have prevented their widespread expl

Reactivity of a Cyclic α-Bromoiminium Bromide towards Nucleophiles

Piperidine-pyrrolidine ring contraction of 1-piperideinium bromide (1) was observed by reaction with aqueous bases, sodium methoxide, phenylhydrazine, (S)-1-phenylethylamine and sodium borohydride, whereas diazomethane addition mainly gave pyrrolopyridine derivative 8.Some stereochemical features of these reactions have been investigated. 1 gave back bromine under suitable conditions.

EVIDENCE FOR A SINGLE ELECTRON TRANSFER ACTIVATION IN THE HYDRIDE TRANSFER FROM AN NADH MODEL COMPOUND TO TETRACYANOETHYLENE

New evidence for a stepwise mechanism which requires a single electron transfer activation in the hydride transfer from an NADH model compound, 1-benzyl-1,4-dihydronicotinamide (BNAH), to tetracyanoethylene (TCNE) has been presented based on the effects of pyridine on the stoichiometry of the overall reaction, the rate constant, and the kinetic isotope effect.