65083-11-6Relevant academic research and scientific papers
Synthesis of the AB-ring of 9,11-secosterols
Aav, Riina,Kanger, T?nis,Pehk, T?nis,Lopp, Margus
, p. 529 - 531 (2007/10/03)
The first total synthesis of AB-ring system of an antiproliferative and cytotoxic 9,11-secosterol 1 is described. Enantiomerically pure (3S,5S,6S,10S)-3,6-diacetoxy-10-methylbicyclo[4.4.0]decan-9-one8 (steroidal numeration) was prepared from (S)-Wieland-Miescher ketone.
