65085-90-7Relevant academic research and scientific papers
A Robust One-Step Approach to Ynamides
Tu, Yongliang,Zeng, Xianzhu,Wang, Hui,Zhao, Junfeng
supporting information, p. 280 - 283 (2018/01/17)
A robust one-step synthetic strategy for ynamide with cheap and easily available stock chemicals vinyl dichlorides and electron deficient amides as the starting material is described. In the absence of transition-metal catalyst, the reaction proceeds under mild reaction conditions in open air and thus rendering a convenient operation. This strategy is not only suitable for both terminal and internal ynamide synthesis but also amenable for large-scale preparation. Broad substrate scopes with respect to vinyl dichloride as well as electron-deficient amide were observed.
Reduction of trihalomethyl carbinols and their acetates, mesylates and tosylates by indium metal
Ranu, Brindaban C.,Samanta, Sampak,Das, Arijit
, p. 5993 - 5995 (2007/10/03)
A study of reduction of trihalomethyl carbinols and their derivatives by indium metal shows that while trichloromethyl carbinols produce a mixture of the corresponding dichloromethyl carbinol and vinylidene dichloride, the acetates, mesylates and tosylate
