65086-97-7Relevant academic research and scientific papers
A NEW SYNTHESIS OF 1-(2,2-DICHLOROVINYL)URACILS BASED ON THE REACTIONS OF 3-tert-BUTYL-6-METHYLURACIL AND 3-tert-BUTYL-5-CHLORO-6-METHYLURACIL WITH TRICHLOROACRYLOYL CHLORIDE
Akhmetov, L. I.,Ivanov, A. V.,Savin, V. P.,Talzi, V. P.
, p. 1759 - 1762 (2007/10/02)
As a result of the reactions of the sodium salts of 3-tert-butyl-6-methyluracil and 3-tert-butyl-5-chloro-6-methyluracil with trichloroacryloyl chloride 1-(2,2-dichlorovinyl)-5-tert-butyl-6-methyluracil and 1-(2,2-dichlorovinyl)-3-tert-butyl-5-chloro-6-methyluracil were obtained instead of the products from N-acylation of the uracils.This corresponds to the reaction of the uracils (I, II) with the dichlorovinylketene formed as a result of the elimination of chlorine by the trichloroacryloyl chloride molecule.
