65094-61-3Relevant academic research and scientific papers
Carbonylation of tertiary carbon radicals: synthesis of lactams
Yin, Zhiping,Zhang, Zhuan,Zhang, Youcan,Dixneuf, Pierre H.,Wu, Xiao-Feng
, p. 4655 - 4658 (2019/05/09)
Herein, we disclose an interesting iron-catalyzed approach for the carbonylation of a tertiary carbon radical. The tertiary carbon radical generated from a 1,5-hydrogen atom transfer can be captured by CO gas smoothly. Various six-membered lactams were constructed chemo-selectively in high yields.
Reaction of Schiff Bases with Acrylamides. Synthesis of 2-Oxotetrahydropyridines
Barluenga, Jose,Muniz, Laudina,Palacios, Francisco,Gotor, Vicente
, p. 65 - 67 (2007/10/02)
Ketimines react with acrylamide and methacrylamide in the presence of aluminium chloride to afford 2-oxotetrahydropyridines by a C-alkylation pathway.
