65094-91-9Relevant academic research and scientific papers
Asymmetric Synthesis of Secondary Alcohols and 1,2-Disubstituted Epoxides via Organocatalytic Sulfenylation
Rota, Filippo,Benhamou, Laure,Sheppard, Tom D.
, p. 33 - 36 (2016)
Enantioenriched secondary alcohols can be prepared via a short reaction sequence involving asymmetric organocatalytic sulfenylation of an aldehyde, organometallic addition, and desulfurization. This process provides access to enantioenriched alcohols with sterically similar groups attached to the alcohol carbon atom. The intermediate β-hydroxysulfides can also serve as precursors to enantioenriched 1,2-disubstituted epoxides via alkylation of the sulfur and subsequent base-mediated ring closure.
Enantioselective Aerobic Epoxidation of Acyclic Simple Olefins Catalyzed by the Optically Active β-Ketoiminato Manganese(III) Complex
Nagata, Takushi,Imagawa, Kiyomi,Yamada, Tohru,Mukaiyama, Teruaki
, p. 1259 - 1262 (2007/10/02)
Enantioselective aerobic epoxidation of acyclic cis-olefins into the corresponding optically active epoxides was carried out with good-to-high enantioselectivities by using a new class of optically active β-ketoiminato manganese(III) complex catalyst, N,N
