65102-39-8Relevant academic research and scientific papers
Unusual reaction behavior of gem -difluorocyclopropane derivatives: Stereoselective synthesis of β-monofluoroallylic alcohols, ethers, esters, and amide
Nihei, Takashi,Hoshino, Tomoko,Konno, Tsutomu
, p. 4170 - 4173 (2014)
On treating gem-difluorocyclopropylstannanes, derived from the radical hydrostannation of gem-difluorocyclopropenes, with 1.5 equiv of MeLi in THF at -78 °C for 5 min, followed by quenching the reaction with various agents, such as H2O, alcohols, carboxylic acids, and tosylamide, the corresponding β-fluoroallylic alcohols, ethers, esters, and amide were obtained with exclusive Z-selectivity in acceptable yields.
Single-Electron-Transfer Pathway in the Coupling of Cyclopropenyl Cations with Organometallic Reagents
Padwa, Albert,Goldstein, Steven I.,Rosenthal, Robert J.
, p. 3278 - 3285 (2007/10/02)
Treatment of diphenylmethylcyclopropenylium perchlorate with various Grignard reagents produced substituted cyclopropenes in excellent yield.Alkyl and vinylic Grignard reagents react at the methylated carbon atom.The substantial increase in formation of t
