651032-57-4Relevant academic research and scientific papers
Synthesis of new (-)-menthylgermanium derivatives and its use in heterogeneous bimetallic catalysis
Faraoni, María B.,Vetere, Virginia,Casella, Mónica L.,Podestá, Julio C.
, p. 3440 - 3444 (2011)
The syntheses and physical properties of tri-(-)-menthylgermanium chloride (2), tri-(-)-menthylmethylgermanium (5), and tri-(-)-menthylgermanium hydride (6) are reported. The preparation of a bimetallic catalyst derived from 5 and Pt supported on SiO
ORGANOGERMANIUM COMPOUNDS AND METHODS FOR THEIR USE
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Page/Page column 33, (2010/02/06)
The invention provides a method for enantioselectively reducing a prochiral carbon centred radical having one or more electron donor groups attached directly to the central prochiral carbon atom of the radical, and/or attached to a carbon atom within 1 to 4 atoms of the central prochiral carbon atom, comprising treating said radical with a chiral non-racemic organogermanium hydride in the presence of a Lewis acid. The invention also provides a novel class of chiral non-racemic organogermanium hydrides and a method of preparing chiral non-racemic organogermanium compounds.
