65108-51-2Relevant academic research and scientific papers
ALKINE UND CUMULENE-XX. TRIMETHYLSILYLALLENE DURCH RETRO-EN-SPALTUNG VON TRIMETHYLSILYLPROPARGYLETHERN
Hopf, Henning,Naujoks, Elke
, p. 609 - 610 (2007/10/02)
The trimethylsilylallenes 3a-f are obtained in excellent yields when thepropargylic precursors 2a-f are subjected to low pressure flow pyrolysis at ca. 620 deg C.
A Simple, New Preparation of α,α-Dimethylallyltrimethylsilane: a Useful Prenylation Reagent
Bennetau, Bernard,Pillot, Jean-Paul,Dunogues, Jacques,Calas, Raymond
, p. 1094 - 1095 (2007/10/02)
Starting from 3-methylbut-1-yn-3-ol, a short synthesis of α,α-dimethylallyltrimethylsilane (a selective prenylation reagent) has been achieved in 47percent overall yield; several other unsaturated organosilicon intermediates of wide potential utility in organic synthesis are also prepared.
