65113-32-8Relevant academic research and scientific papers
Macrocyclic diphosphine ligands in asymmetric carbon-carbon bond-forming reactions
Widhalm, Michael,Wimmer, Petra,Klintschar, Gerd
, p. 167 - 178 (1996)
Seven chiral macrocyclic ligands with potential O2P2 and N2P2 coordination sites owing their chirality from the incorporation of an axial-chiral binaphthyl unit were used as chiral auxiliaries in transition meta
Looking for 1,3-di- and 1,2,3-triphosphindolide ions
Maigrot, Nicole,Charrier, Claude,Ricard, Louis,Mathey, Francois
, p. 853 - 858 (2007/10/03)
The reaction of 1,2-bis(lithiophenylphosphino)benzene 1 with dichloromethane leads to a cis-trans mixture of 1,3-diphenyl-2,3-dihydro-1H-1,3-benzodiphosphole 2.The reaction of 2, first with Et2NLi, then with an excess of lithium leads to the parent 1,3-di
Reaction of Alkali Metal Phosphides with White Phosphorus, II. Formation and Structure of Lithio-2,3-dihydro-1,3-diphenyl-1H-benzotriphosphole
Schmidpeter, Alfred,Burget, Guenther,Sheldrick, William S.
, p. 3849 - 3855 (2007/10/02)
The o-phenylenebis(lithium phosphide) 1 leads to a disproportionation of white phosphorus by formally taking up P+ and leaving P73-.The resultant title compound 2 may be converted to different derivatives 3 by reaction with electrophiles.According to a crystal structure analysis 2 (THF)3 consists of isolated ion pairs with Li singly coordinated to the central phosphorus.
High-Dilution Synthesis of 14-Membered Tetradentate Macrocycles Incorporating the Diars Moiety
Kyba, Evan P.,Chou, Shang-Shing P.
, p. 860 - 863 (2007/10/02)
Six 14-membered tert-arsino-containing macrocycles are described.These are the 2,17-dimethyl-2,17-diarsa-6,13-diheteratricyclo7,12>docosa-7(12),8,10,18(1),19,21-hexaenes, where 6,13-dihetera is dioxa, dithia, bis(methylarsa) and bis(ph
