65121-64-4Relevant academic research and scientific papers
Diels-Alder reaction rate in the solid state and the evidence of the location of molecular complexes between the reagents on the reaction pathway
Kiselev, Vladimir D.,Kolesnikova, Anastasia O.,Dinikaev, Ildar F.,Shulyatiev, Alexey A.,Klimovitskii, Alexander E.,Kornilov, Dmitry A.
, p. 207 - 212 (2021)
The rate of reactions in the solid phase with uniform grinding of crystals of dienes, anthracene, and 9,10-dimethylanthracene, with dienophiles, tetracyanoethylene, N-phenylmaleimide, and 4-phenyl-1,2,4-triazoline-3,5-dione, has been studied. It was shown
BISREAGENTS IN THE DIELS-ALDER REACTION VI. KINETICS AND THERMOCHEMISTRY OF REACTIONS OF POLYMETHYLCYCLOPENTADIENES AND SOME BISDIENES WITH SOME DIENOPHILES
Kiselev, V. D.,Sakhabutdinov, A. G.,Shakirov, I. M.,Konovalov, A. I.
, p. 1437 - 1443 (2007/10/02)
From kinetic and thermochemical data on Diels-Alder reactions with the participation of 1,2,3,4-tetra-, penta-, and hexa-methylcyclopentadienes, 1,2-bis(pentamethylcyclopentadienyl)ethane and 1,4-bis(pentamethylcyclopentadienyl)butane it follows that these dienes are highly reactive and with dienophiles form addition products that are fairly stable to decomposition.By the reactions of α,ω-bis(pentamethylcyclopentadienyl)-ethane and -butane with N,N'-m-phenylenebismaleimide products with a molecular weight of up to 80,000 were obtained.
